Recyclable and highly active cationic 2,2′-bipyridyl palladium(II) catalyst for Suzuki cross-coupling reaction in water

Wei Yi Wu; Shao Nung Chen; Fu Yu Tsai

doi:10.1016/j.tetlet.2006.10.127

Recyclable and highly active cationic 2,2′-bipyridyl palladium(II) catalyst for Suzuki cross-coupling reaction in water

Wei Yi Wu
, Shao Nung Chen
, Fu Yu Tsai

分子科學與工程系

研究成果: 期刊貢獻 › 文章 › 同行評審

96 引文斯高帕斯（Scopus）

摘要

A water-soluble and air-stable palladium(II)/cationic 2,2′-bipyridyl catalyst is proven to be a recyclable and extremely active catalyst for Suzuki reaction in aqueous and aerobic conditions. The conveniently prepared catalyst showed little loss in the catalytic process of the coupling between 4-bromoacetophenone and phenylboronic acid after five cycles. For the reactions of aryl chlorides, biaryls were formed in high yields under refluxing temperature in the presence of TBAB.

原文	English
頁（從 - 到）	9267-9270
頁數	4
期刊	Tetrahedron Letters
卷	47
發行號	52
DOIs	https://doi.org/10.1016/j.tetlet.2006.10.127
出版狀態	Published - 25 12月 2006

文獻附註

Funding Information:
The research was financially supported by the National Science Council of Taiwan (NSC94-2113-M-027-002). We gratefully thank Professor Kou-Yuan Hwa for her helpful suggestion.

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10.1016/j.tetlet.2006.10.127

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title = "Recyclable and highly active cationic 2,2′-bipyridyl palladium(II) catalyst for Suzuki cross-coupling reaction in water",

abstract = "A water-soluble and air-stable palladium(II)/cationic 2,2′-bipyridyl catalyst is proven to be a recyclable and extremely active catalyst for Suzuki reaction in aqueous and aerobic conditions. The conveniently prepared catalyst showed little loss in the catalytic process of the coupling between 4-bromoacetophenone and phenylboronic acid after five cycles. For the reactions of aryl chlorides, biaryls were formed in high yields under refluxing temperature in the presence of TBAB.",

author = "Wu, \{Wei Yi\} and Chen, \{Shao Nung\} and Tsai, \{Fu Yu\}",

note = "Funding Information: The research was financially supported by the National Science Council of Taiwan (NSC94-2113-M-027-002). We gratefully thank Professor Kou-Yuan Hwa for her helpful suggestion. ",

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AU - Wu, Wei Yi

AU - Chen, Shao Nung

AU - Tsai, Fu Yu

N1 - Funding Information: The research was financially supported by the National Science Council of Taiwan (NSC94-2113-M-027-002). We gratefully thank Professor Kou-Yuan Hwa for her helpful suggestion.

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N2 - A water-soluble and air-stable palladium(II)/cationic 2,2′-bipyridyl catalyst is proven to be a recyclable and extremely active catalyst for Suzuki reaction in aqueous and aerobic conditions. The conveniently prepared catalyst showed little loss in the catalytic process of the coupling between 4-bromoacetophenone and phenylboronic acid after five cycles. For the reactions of aryl chlorides, biaryls were formed in high yields under refluxing temperature in the presence of TBAB.

AB - A water-soluble and air-stable palladium(II)/cationic 2,2′-bipyridyl catalyst is proven to be a recyclable and extremely active catalyst for Suzuki reaction in aqueous and aerobic conditions. The conveniently prepared catalyst showed little loss in the catalytic process of the coupling between 4-bromoacetophenone and phenylboronic acid after five cycles. For the reactions of aryl chlorides, biaryls were formed in high yields under refluxing temperature in the presence of TBAB.

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JO - Tetrahedron Letters

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IS - 52

ER -

Recyclable and highly active cationic 2,2′-bipyridyl palladium(II) catalyst for Suzuki cross-coupling reaction in water

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