Nano-sizing titanium into titanium carbide by 1-chlorobutane

Yu Hsu Chang; Hsin Tien Chiu

doi:10.1557/JMR.2002.0403

Nano-sizing titanium into titanium carbide by 1-chlorobutane

Yu Hsu Chang
, Hsin Tien Chiu

資源工程研究所

研究成果: 期刊貢獻 › 文章 › 同行評審

20 引文斯高帕斯（Scopus）

摘要

TiC nanoparticles (average diameter 10-150 nm) were prepared by reacting bulk Ti powders (average diameter 20 μm) with gaseous 1-chlorobutane at a relatively low temperature (1073-1273 K). 1-Chlorobutane provided the carbon atom in the TiC and the chlorine atom that assisted the shrinking of the size of the original Ti powders. The apparently simple procedure is a complex heterogeneous process combining etching, deposition, and carburization reactions.

原文	English
頁（從 - 到）	2779-2782
頁數	4
期刊	Journal of Materials Research
卷	17
發行號	11
DOIs	https://doi.org/10.1557/JMR.2002.0403
出版狀態	Published - 11月 2002

文獻附註

Funding Information:
The authors thank the National Science Council of Taiwan, Republic of China, for financial support (Grant NSC-892113-M-009-013). Professor Chi-Young Lee is appreciated for FTIR consulting.

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10.1557/JMR.2002.0403

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AB - TiC nanoparticles (average diameter 10-150 nm) were prepared by reacting bulk Ti powders (average diameter 20 μm) with gaseous 1-chlorobutane at a relatively low temperature (1073-1273 K). 1-Chlorobutane provided the carbon atom in the TiC and the chlorine atom that assisted the shrinking of the size of the original Ti powders. The apparently simple procedure is a complex heterogeneous process combining etching, deposition, and carburization reactions.

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Nano-sizing titanium into titanium carbide by 1-chlorobutane

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