Comparing natural red soil and irons for removal of phosphorus from wastewater using the multi-soil-layering system and its economic analysis

The study uses an emerging soil treatment technology, the Multi-Soil Layering System (MSL), which is composed of the zeolite permeability layers (PL) and the soil mixture block layers (SMB). The experimental results show that the SMBs with iron particle (SMB-I) removed more than 83% of the total phosphorus (P) pollution in the water, and the outflow sewage concentration is 9.6 mg/L. In contrast, the SMBs with red clay (SMB-R) has 23% removal rate, and the outflow sewage concentration is 46.45 mg/L. Only 0.013 mg/L Fe concentration was detected in the SMB-R system and release of Fe from red soil is hardly achieved under neutral water environment. The SMB-R and SMB-I systems reduced 108.89 mg/g and 20.93 mg/g respectively and the SMB-R had higher removal efficiency of P per gram released Fe. The chromaticity problem of the effluent water in the SMB-I is up to 225 platinum cobalt, and that of the SMB-R is 172 platinum cobalt. Adding 10 g oyster shell (slice-only) and/or 0.65 g polyglutamic acid have effectively removed up to 99% 25-mg/L Fe in the effluent water; the chromaticity problem caused by Fe effluent was successfully solved. Furthermore, the iron particle has the highest unit cost among the materials in the SMBs (US$1.47/kg in lab and US$0.12/kg in field). Removal of 1 mg/L TP in the MSL system costs US$0.036 (by lab) in terms of removal TP rate in the laboratory was 83% and is economically feasible in field development.